National Institute of Advanced Industrial Science and Technology (AIST) This page is a page of the former research institute. We stopped updating on March 31.2001.
E-mail to webmaster (Japanese) E-mail to webmaster (English)

Laser-jet Photolysis of 1,8-Bis(substituted-methyl) -naphthalenes: the Effect of Heteroatom Leaving Groups on the Two-photon C-C Bond Formation

A. Ouchi and W. Adam
[J. Chem. Soc., Chem. Commun., No.7, pp.628-629, 1993]


The formation of acenaphthene 4 by laser-jet photolysis of 1,8-bis(phenoxymethyl)-(1a), 1,8-bis(phenylthiomethyl)-(1b) and 1,8-bis(phenylselenomethyl)-naphthalene(1c) strongly depends on the heteroatom of the leaving group; the increasing order of naphthalene consumption was 1c ≈ 1b ľ 1a, whereas that for the formation of 4 was 1c ľ 1a ľ 1b.