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Chromogenic 1, 10-Phenanthroline for Determination of Lithium Ion

H. Sugihara, J. Kajiwara, S. Akabori, and K. Hiratani
[Chem. Lett. pp. 15-16, 1996]


A new chromogenic 1, 10-phenanthroline bearing picrylamino residue displays a striking lithium ion-selective shift in maximum absorbance in the presence of base upon addition of lithium ions; upon lithium complexation the color of the solution changes from pale yellow to brownish red, the color density being dependent on lithium ion concentration.


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