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Two-DemensIon Arry of SIlver NanopartIcles

Koji Abe, T. Hanada, Y. Yoshida, N. Tanigaki, H. Takiguchi,
H. Nagasawa, M. Nakamoto, T. Yamaguchi, and K. Yase
[Thin Solid Films, Vol. 329, pp. 524-527, 1998]


The silver salts of fatty acids were thermally decomposed at 250 in an atmosphere of nitrogen to form silver nanoparticles with a size of 5 nm. The particles suspended in toluene put on a hydrophilic surface of plasma-polymerized film of osmium tetraoxide and on a water surface to form a two-dimensional array. The nanoparticles repelled each other with a distance of 2.8-3.5 nm depending on the length of the alkyl chain. The surface pressure-area isotherms were measured to confirm the condensation mechanism of two-dimensional arrangement of nanoparticles surrounded by alkyl moieties.


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