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Thermal Behavior of alpha-Alkylated Oligothiophenes

R. Azumi, G. Gotz, and P. Bauerle
[Synthetic Metals, Vol. 101, No. 1, pp. 544-545, 1999]


The thermal behavior of several a-alkylated quaterthiophenes is investigated. Polarizing microscopy and differential scanning calorimetry reveal that dipropylquaterthiophene exhibits a nematic liquid crystalline phase while oligothiophenes bearing longer alkyl chains have more ordered high temperature phases.


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